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81.
Contrasting tourmaline types from peraluminous granites: a case study from Moslava?ka Gora (Croatia)
Two texturally and chemically distinct types of tourmaline are found inside peraluminous granites of the Moslava?ka Gora, Croatia: nodular tourmaline in the two-mica granite and disseminated tourmaline in the cross-cutting leucogranite dykes. Both tourmaline types belong to alkali tourmaline group, nodular tourmaline being dravite to schorl and disseminated tourmaline corresponding to schorl. Comparison of characteristic parameters of nodular (Nt) and disseminated tourmaline (Dt) shows significant differences in #Fe (0.40?C0.65 for Nt vs. 0.74?C0.85 in Dt) along with variations in the calculated X-site vacancy (0.22?C0.37 pfu in Nt and 0.33?C0.44 in Dt) and ??/(??+Na) ratio (0.23?C0.40 in Nt and 0.34?C0.45 in Dt). Disseminated tourmaline from the MG leucogranites is regarded as an early crystallized magmatic phase, while the interstitial tourmaline from the cores of tourmaline nodules originated from more complex mineralogical and chemical interactions inside the two-mica granite melt. Major element gain (Mg) and loss (Fe, Ca, Na, K) for the ??idealized nodule?? (34 vol. % core + 66 vol. % halo) when compared to the host granite shows that the nodule??s volume is not a completely independent and closed system. Based on the observed characteristics, nodule??s halo can be considered as a ??transitional zone?? between the tourmaline-bearing core and the host granite, texturally and mineralogically related to the host two-mica granite, chemically being an integral part of the nodule??s volume at the same time. 相似文献
82.
N. V. Chukanov A. A. Mukhanova R. K. Rastsvetaeva D. I. Belakovsky S. M?ckel O. V. Karimova S. N. Britvin S. V. Krivovichev 《Geology of Ore Deposits》2011,53(7):583-590
Oxyphlogopite is a new mica-group mineral with the idealized formula K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2. The holotype material came from a basalt quarry at Mount Rothenberg near Mendig at the Eifel volcanic complex in Rhineland-Palatinate,
Germany. The mineral occurs as crystals up to 4 × 4 × 0.2 mm in size encrusting cavity walls in alkali basalt. The associated
minerals are nepheline, plagioclase, sanidine, augite, diopside, and magnetite. Its color is dark brown, its streak is brown,
and its luster is vitreous. D
meas = 3.06(1) g/cm3 (flotation in heavy liquids), and D
calc = 3.086 g/cm3. The IR spectrun does not contain bands of OH groups. Oxyphlogopite is biaxial (negative); α = 1.625(3), β = 1.668(1), and
γ = 1.669(1); and 2V
meas = 16(2)° and 2V
calc = 17°. The dispersion is strong; r < ν. The pleochroism is medium; X > Y > Z (brown to dark brown). The chemical composition is as follows (electron microprobe, mean of 5 point analyses, wt %; the ranges
are given in parentheses; the H2O was determined using the Alimarin method; the Fe2+/Fe3+ was determined with X-ray emission spectroscopy): Na2O 0.99 (0.89–1.12), K2O 7.52 (7.44–7.58), MgO 14.65 (14.48–14.80), CaO 0.27 ((0.17–0.51), FeO 4.73, Fe2O3 7.25 (the range of the total iron in the form of FeO is 11.09–11.38), Al2O3 14.32 (14.06–14.64), Cr2O3 0.60 (0.45–0.69), SiO2 34.41 (34.03–34.66), TiO2 12.93 (12.69–13.13), F 3.06 (2.59–3.44), H2O 0.14; O=F2 −1.29; 99/58 in total. The empirical formula is (K0.72Na0.14Ca0.02)(Mg1.64Ti0.73Fe0.302+ Fe0.273+Cr0.04)Σ2.98(Si2.59Al1.27Fe0.143+ O10) O1.20F0.73(OH)0.07. The crystal structure was refined on a single crystal. Oxyphlogopite is monoclinic with space group C2/m; the unit-cell parameters are as follows: a = 5.3165(1), b = 9.2000(2), c = 10.0602(2) ?, β = 100.354(2)°. The presence of Ti results in the strong distortion of octahedron M(2). The strongest lines of the X-ray powder diffraction pattern [d, ? (I, %) [hkl]] are as follows: 9.91(32) [001], 4.53(11) 110], 3.300(100) [003], 3.090(12) [112], 1.895(21) [005], 1.659(12) [−135], 1.527(16)
[−206, 060]. The type specimens of oxyphlogopite are deposited at the Fersman Mineralogical Museum in Moscow, Russia; the
registration numbers are 3884/2 (holotype) and 3884/1 (cotype). 相似文献
83.
The use of spectral analysis-based exact solutions to characterize topography-controlled groundwater flow 总被引:2,自引:1,他引:1
Spectral analysis enhances the ability to analyze groundwater flow at a steady state by separating the top boundary condition into its periodic forms. Specifically, spectral analysis enables comparisons of the impact of individual spatial scales on the total flow field. New exact spectral solutions are presented for analyzing 3D groundwater flow with an arbitrarily shaped top boundary. These solutions account for depth-decaying, anisotropic and layered permeability while utilizing groundwater flux or the phreatic surface as a top boundary condition. Under certain conditions, groundwater flow is controlled by topography. In areas where the groundwater flow is controlled by the topography, the unknown water table is often approximated by the topography. This approximation induces a systematic error. Here, the optimal resolution of digital elevation models (DEMs) is assessed for use as a top boundary in groundwater flow models. According to the analysis, the water-table undulation is smoother than the topography; therefore, there is an upper limit to the resolution of DEMs that should be used to represent the groundwater surface. The ability to represent DEMs of various spectral solutions was compared and the results indicate that the fit is strongly dependent on the number of harmonics in the spectral solution. 相似文献
84.
Catarina Vinagre João Salgado Henrique N. Cabral Maria J. Costa 《Estuaries and Coasts》2011,34(4):663-674
River flow variability is known to influence estuarine production, yet knowledge on its effect upon estuarine food webs dynamics
is still scarce. Stable carbon and nitrogen isotopes were used to assess the effect of river flow in the connectivity and
food web interactions between the two main fish nursery areas of the Tagus estuary. The aims of the present work were to investigate
the seasonal variation in food web structure and the exchange rate of individuals of marine juvenile fish among estuarine
nurseries, to compare the spring of a rainy year (2001) with that of an average year (2000), and to investigate the impact
of the winter floods of 2001. A low level of connectivity was observed for the fish species that use these areas as nurseries.
In low river flow conditions, two isotopically distinct food webs were established in each nursery area. These food webs were
very sensitive to small variations in the freshwater input. Winter floods seem to disrupt the localized food webs that are
established in low river flow periods, leading to the re-establishment of a wider food web. While in rainy years this wide
food web is maintained until spring, in average years the food web undergoes fragmentation into two localized and isotopically
distinctive food webs. The increase in frequency of droughts due to climate change should lower the connectivity of the estuarine
fish nurseries food webs, causing habitat fragmentation and consequent loss in complexity and resilience. 相似文献
85.
Complex system approach to interpretation of monitoring time series: two case histories from NW Bohemia 总被引:1,自引:1,他引:0
Ever wider implementation of information technologies is flooding us by monitoring data. To an efficient risk management,
those data have to be processed and assessed in the same rate as they are recorded and transported. Paper demonstrates some
methods dealing with intrinsic, nonlinear dynamics of slope system for computerized safety assessment of monitoring time series,
their modeling and early warning launching. Analysis and modeling of phase changes – i.e. specific transient states between
different developmental stages of dynamics of unstable slope systems, enabled to fix new types of precursors for rock fall
warning and to enhance time prediction of rock fall occurrence. Mathematically well based, novel numerical and topological
methods from the toolbox of complex system theory were successfully implemented to that challenge. Their pattern-recognition
ability, i.e., diagnostic sensitivity, and more realistic results of modeling of time series relevant patterns have reached
beyond ranges of regularly used—both the idea- and the data-driven—methods. Moreover, results yielded by phase space analyses
are in good agreement with the ones by numerical fractal analyses. Obtained results have strengthened the primary, mainly
theoretically based hypothesis; the dynamics of an unstable rock slope has to be considered as behavior of nonlinear, dissipative,
non-equilibrium, self-organizing complex system. Correspondingly to the theoretical assumptions, two qualitatively different
types of slope system dynamics—near to equilibrium and far from equilibrium states, were identified. All field monitoring
data used originated in practice of highly automated, integrated IT system of monitoring assessment, and management of rock
fall hazard at sandstone rock walls in the NW Bohemia. 相似文献
86.
The material of Hispanomys decedens (Rodentia, Cricetodontinae) from La Grive-Saint Alban (France) is described in detail for the first time. H. decedens, which is one of the oldest species of the genus, shows the primitive character states that are typical of the Aragonian congeneric species, such as the mesolophs and labial cingula surrounding the upper molar valleys. The detailed examination of the teeth of H. decedens shows that this taxon is a good candidate ancestor for H. aragonensis. 相似文献
87.
Constant shear drained tests (CSD) are probably the most suitable to simulate the strength and deformation behaviour of soils
in slopes under water infiltration conditions or lateral stress relief. This is significant because soil behaviour following
a CSD stress path could differ from that of traditional compression triaxial tests. In this paper, CSD tests on sand following
an alternative procedure are presented and discussed. The modified CSD tests were conducted by increasing the pore water pressure
at a constant rate from one end of the specimen with water free to drain from the opposite end. Among the results from specimens
consolidated at variable initial void ratios and principal stress ratios it was revealed that specimens showed a tendency
to dilate even for loose sands; failure was reached at low axial strains; and a pre-failure type of instability could be identified.
The modified procedure has the potential to provide new insights into the failure mechanisms of slopes under a water infiltration
condition. 相似文献
88.
The shear band (SB) spacing phenomenon in geomaterials is addressed in this paper under plane strain extensional conditions.
On the basis of sand box observations, a method is proposed for the prediction of the spacing between shear bands based on
the so-called “bookshelf” deformation mechanism. The proposed method is based on the assumption that the material is softening
inside the shear bands whereas outside the SB it undergoes elastic unloading. The underlying assumption for the prediction
of SB spacing is that the material reaches the lowest possible energy rate. An analytical expression for the determination
of the shear band spacing is presented taking into account the plane strain extensional deformation of the specimen. The friction
due to the normal off-plane shear acting on the boundaries is then taken into account. 相似文献
89.
This paper describes the implementation of process-based models reflecting relative groundwater nitrate vulnerability of the
shallow alluvial Lower Savinja Valley (LSV) aquifer in Slovenia. A spatially explicit identification of the potentially vulnerable
priority areas within groundwater bodies at risk from a chemical point of view is being required for cost-effective measures
and monitoring planning. The shallow LSV unconfined aquifer system consists of high-permeable Holocene and middle- to low-permeable
Pleistocene gravel and sand, with a maximum thickness of about 30 m, mainly covered by shallow eutric fluvisoils or variously
deep eutric cambisoil. The hydrogeological parameters, e.g. the depth to the groundwater, hydrological role of the topographic
slope, etc. usually used in different point count schemes are, in the case of the lowland aquifer and shallow groundwater,
spatially very uniform with low variability. Furthermore, the parametric point count methods are generally not able to illustrate
and analyze important physical processes, and validation of the results is difficult and expensive. Instead of a parametric
point count scheme, we experimentally used the Arc-WofE extension for weights-of-evidence (WofE) modelling. All measurement
locations with a concentration higher than the value of 20 mg NO3
− per litre of groundwater have been considered as training points (173), and the three process-based models generalized output
layers of groundwater recharge (GROWA), nitrate leached from the soil profile (SWAT) and groundwater flow velocity (FEFLOW),
served as evidential themes. The technique is based on the Bayesian idea of phenomena occurrences probability before (prior
probability) and after consideration of any evidential themes (posterior probability), which were measured by positive and
negative weights as an indication of the association between a phenomena and a prediction pattern. The response theme values
describe the relative probability that a 100 × 100 m spatial unit will have a groundwater nitrate concentration higher than
the training points’ limit values with regard to prior probability value. The lowest probability of groundwater nitrate occurrence
is in the parts of the LSV aquifer, which are known as anoxic condition areas with very likely denitrification processes.
The cross-validation of the dissolved oxygen and dissolved nitrate response theme confirmed the accuracy of the groundwater
nitrate prediction. The WofE model results very clearly indicate regional groundwater nitrate distribution and enable spatial
prediction of the probability for increased groundwater nitrate concentration in order to plan the groundwater nitrate reduction
measures and optimize the programme for monitoring the effects of these measures. 相似文献
90.